Maleic Anhydride (MA)
Product Profile
Apply for Sample| Names | |
|---|---|
| Preferred IUPAC name | 2,5-Furandione |
| Other names | 2,5-Furandione cis-Butenedioic anhydride Toxilic anhydride Maleic acid anhydride Dihydro-2,5-dioxofuran |
| Pronunciation | /məˌliːɪk ænˈhaɪdraɪd/ |
| Identifiers | |
| CAS Number | 108-31-6 |
| Beilstein Reference | Beilstein Reference: 77342 |
| ChEBI | CHEBI:28243 |
| ChEMBL | CHEMBL1402 |
| ChemSpider | 546073 |
| DrugBank | DB13821 |
| ECHA InfoCard | 100.003.278 |
| EC Number | 204-419-1 |
| Gmelin Reference | 613 |
| KEGG | C00993 |
| MeSH | D008288 |
| PubChem CID | 962 |
| RTECS number | OU6930000 |
| UNII | WSF4401J6B |
| UN number | 2215 |
| Properties | |
| Chemical formula | C4H2O3 |
| Molar mass | 98.06 g/mol |
| Appearance | White crystalline solid |
| Odor | Pungent, choking odor |
| Density | 1.48 g/cm³ |
| Solubility in water | Reacts with water |
| log P | -0.74 |
| Vapor pressure | 0.4 mmHg (25°C) |
| Acidity (pKa) | 1.9 |
| Basicity (pKb) | 1.05 |
| Magnetic susceptibility (χ) | -53.2×10⁻⁶ cm³/mol |
| Refractive index (nD) | 1.555 |
| Viscosity | 2.5 cP (25°C) |
| Dipole moment | 2.70 D |
| Thermochemistry | |
| Std molar entropy (S⦵298) | S⦵298 = 260.5 J·mol⁻¹·K⁻¹ |
| Std enthalpy of formation (ΔfH⦵298) | -458.7 kJ/mol |
| Std enthalpy of combustion (ΔcH⦵298) | −1790 kJ/mol |
| Hazards | |
| GHS labelling | GHS02, GHS05, GHS07, GHS08 |
| Pictograms | GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H302, H314, H317, H334, H335 |
| Precautionary statements | P261, P280, P305+P351+P338, P304+P340, P337+P313, P310, P302+P352, P362+P364, P314, P501 |
| NFPA 704 (fire diamond) | 2-2-2-W |
| Flash point | 102 °C |
| Autoignition temperature | 435 °C |
| Explosive limits | '1.4–7.1% (in air)' |
| Lethal dose or concentration | LD50 oral rat: 2,400 mg/kg |
| LD50 (median dose) | 2400 mg/kg (rat, oral) |
| NIOSH | NIOSH: KJ5775000 |
| PEL (Permissible) | PEL (Permissible Exposure Limit) of Maleic Anhydride (MA) is 1 ppm (parts per million) as an 8-hour TWA (Time Weighted Average) according to OSHA. |
| REL (Recommended) | 250 mg/m³ |
| IDLH (Immediate danger) | 250 ppm |
| Related compounds | |
| Related compounds | Maleic acid Phthalic anhydride Fumaric acid Succinic anhydride Maleimide Itaconic anhydride Citric acid Acrylic acid |
Chemical ID: CAS Formula HS Code Database
Product Identification for Maleic Anhydride (MA)
| Attribute | Manufacturer Commentary |
|---|---|
| Product Name & IUPAC Name |
Maleic Anhydride IUPAC: Furan-2,5-dione |
| Chemical Formula |
C4H2O3 The empirical formula holds for all industrial grades. During production, off-gas management and oxygen ratios are significant for optimal yield. |
| Synonyms & Trade Names |
Common Synonyms: Cis-butenedioic anhydride, toxilic anhydride Trade names and designations may vary between regions and customer requirements, especially in polymer and resin markets. |
| HS Code & Customs Classification |
HS Code: 2917.14 International shipments require correct classification to comply with national customs authorities. Regional rules may create variations in sub-categories, but most import/export declarations fall under this code. |
Manufacturer Industrial Perspective
Observation in Industrial Production
Maleic anhydride is manufactured by the oxidation of n-butane or benzene, with n-butane oxidation now predominating due to economics and lower hazardous by-products. Selection of process route depends on plant configuration, feedstock pricing, and emission control frameworks. Catalytic oxidation parameters—including temperature control, oxygen partial pressure, and catalyst maintenance—form the foundation for typical grade consistency.
Grade-Dependency and Application-Sensitivity
Product purity, color, and trace contaminant levels are the main differentiators between grades. High-purity material is mandatory for food contact polymers and synthetic resins, whereas agricultural and surfactant applications may tolerate wider impurity ranges. End-use sectors define the necessary acid value, residual solvent content, and presence of maleic acid hydrolysate, as well as moisture management thresholds during packaging. Custom blending practices rely on detailed customer specifications, with quality control adjusting to incorporate batch-to-batch testing of these factors.
Storage, Handling, and Downstream Processing
Maleic anhydride solidifies at room temperature; thermal maintenance is essential in bulk handling infrastructure. Material transfers, packaging, and shipment configurations adapt according to product grade and receiving customer technical requirements. Moisture ingress triggers hydrolysis to maleic acid, which affects downstream polymerization or resins, prompting desiccation protocols in drums and ISO tanks. Manufacturing deploys closed transfer systems and nitrogen blanketing for sensitive grades destined for high-end composite materials.
Process Controls, Raw Materials, and Quality Assurance
Raw n-butane quality, trace sulfur content, and absence of silicon-based lubricants in compressors are primary QA focal points for minimizing catalyst fouling and off-grade batches. Inline analyzers and automated GC measurements track maleic anhydride purity, organic by-product profiles, and residual oxygen at reactor exit. Purification integrates fractional condensation and scrubbing. Release criteria benchmark against customer-contracted parameters, with secondary internal thresholds addressing shipment stability during transit in humid climates.
Technical Properties, Manufacturing Process & Safety Guidelines of Maleic Anhydride (MA)
Physical & Chemical Properties
Physical State & Appearance
In factory settings, maleic anhydride is seen as white crystalline flakes or, at higher temperatures, as a clear molten liquid with a pungent, irritating odor. Physical form is determined by temperature control during production and downstream handling. Melting point is typically around 52°C, requiring equipment rated for low-temperature phase change solid handling. Volatility increases rapidly as temperatures rise, with boiling point near 202°C. Packing lines handle both flakes and molten forms depending on supply chain demands.
Product density and color vary depending on raw material purity and plant operation discipline. Density for crystalline form sits near 1.48 g/cm³, but hot-melt handling targets precise calibration to prevent accumulation or choking in pipes. Equipment surfaces must tolerate minor deposit formation and be easily cleaned during maintenance.
Chemical Stability & Reactivity
Maleic anhydride reacts aggressively with water, forming maleic acid. Plant operators must strictly avoid moisture ingress during filling and storage, with positive pressure dry air or inert gas blanketing used to prevent unwanted hydrolysis. Product reacts strongly with bases and exothermically with alcohols and amines—pipework and valves in contact must not use incompatible elastomers or alloys. Heat-sensitive, so process upsets leading to local hot spots can trigger decomposition, causing emission of acrid fumes.
Solubility & Solution Preparation
Maleic anhydride is nearly insoluble in cold water but dissolves on slow hydrolysis. Mixing with water in controlled reactors at defined rates is standard for downstream maleic acid production. Industrial solvent selection focuses on high purity to prevent side reactions affecting downstream formulations, especially for resins and surfactants.
Technical Specifications & Quality Parameters
Specification Table by Grade
Typical grades include industrial, chemical, and polymerization grades. Color, purity, and ash content separate these classes. Color (APHA or Pt-Co), acid number, and residual acidity are directly relevant for specific customer formulations. Detailed specification tables reflect both international and local standards, customer supply contracts, and end-use applications, especially for resin, additive, or fine chemical intermediates.
Impurity Profile & Limits
Impurity content originates from feedstock variability and reactor design. Typical monitoring targets include maleic acid, fumaric acid, phthalic anhydride, and organic acids. Every release batch undergoes quantitative testing, focusing on total volatiles and organic residue. Critical thresholds vary by application—resin synthesis needs minimal organic byproducts to avoid polymer yellowing.
Test Methods & Standards
Product release testing often relies on titrimetric analysis, spectrophotometry (for color/clarity), GC/HPLC for trace impurities, and Karl Fischer for water. Final test methods match specific market standards, supplier-customer technical agreements, and regulatory requirements. Standard selection recognizes both local and international adoption in specification sheets.
Preparation Methods & Manufacturing Process
Raw Materials & Sourcing
Commercial production draws on n-butane or benzene as feedstock, based on regional cost, availability, and downstream integration. Management of olefin stream composition and contaminant profile is central to reaction selectivity and yield maintenance. Supplier qualification for raw material purity reduces off-grade formation.
Synthesis Route & Reaction Mechanism
The principal synthesis route is continuous vapor phase catalytic oxidation using air or oxygen with a vanadium-phosphorus oxide catalyst system. Plant operators tightly control air/fuel ratios and temperature profile to optimize yield while limiting byproduct formation such as CO2 and phthalic anhydride. Reaction outcomes hinge on precise residence time, gas flow, and catalyst activity management.
Process Control & Purification
In-process controls track reactor temperature, pressure, oxygen partial pressure, and catalyst performance. Hot gas streams undergo condensation and scrubbing to harvest product without excessive hydrolysis. Off-gas treatment systems target emission compliance. Multiple recrystallization or distillation steps refine final purity, with continuous monitoring for organic and inorganic byproducts.
Quality Control & Batch Release
Every batch undergoes systematic QC, including visual inspection for color, titration for anhydride/acidity balance, and purity tests focused on grade-specific thresholds. Traceability systems document all raw materials, process batch parameters, and QC findings. Release conformity always aligns with customer contract or internal standard, especially for food-contact or polymer synthesis grades.
Chemical Reactions & Modification Potential
Typical Reactions
Maleic anhydride undergoes hydrolysis with water, Diels-Alder reactions with dienes, and addition to alcohols and amines. Reactivity forms the backbone of unsaturated polyester resin, agricultural intermediate, and surfactant production. Modification potential relies on strict control of moisture, temperature, and reagent addition to avoid side product formation.
Reaction Conditions
Many reactions use organic solvents or run solvent-free for resin synthesis, with catalyst selection tailored to the intended transformation. Temperature, catalyst type, and reagent purity influence conversion rate and byproduct minimization, justifying closed-loop process analytics in automated units.
Derivatives & Downstream Products
Key products formed include fumaric acid, succinic acid, tetrahydrofuran, and a range of unsaturated polyester resins. Each application demands a unique impurity and color threshold, with modification steps based on integrating feedback from downstream processing plants.
Storage & Shelf Life
Storage Conditions
Product must remain dry and sealed, as moisture triggers unwanted hydrolysis. Storage tanks and bins use dry air or inert gas blanketing. Temperature control prevents liquefaction and degradation; warehouse standards prioritize low humidity and light avoidance to minimize discoloration.
Container Compatibility
Mild steel lined with resistant coatings, stainless steel, or high-grade polymer containers ensure mechanical strength and chemical compatibility, especially for molten transfer lines. Packing integrity prevents solid bridge formation or off-gas accumulation.
Shelf Life & Degradation Signs
Shelf life depends greatly on grade, package integrity, and climate conditions. Main degradation indicators include caking, yellowing, and increase in maleic acid content. Routine checks monitor color shift and surface condition for long-term stored product.
Safety & Toxicity Profile
GHS Classification
Maleic anhydride ranks as hazardous under GHS, requiring strict adherence to labeling, handling, and PPE. Classification reflects its acute inhalation and skin/eye irritation potential.
Hazard & Precautionary Statements
Direct skin or inhalation exposure triggers sensitization or severe irritation, handled with mandatory protective clothing, eye protection, and local exhaust ventilation. Plant safety rules target leak detection, emergency flushing stations, and continuous air monitoring wherever open handling occurs.
Toxicity Data
Inhalation presents the primary workplace hazard due to vapor irritation. Toxicity data from animal and human studies reinforce exposure minimization requirements in process, packaging, and lab areas. Specific exposure limits depend on jurisdictional standards and are integrated within local safety programs.
Exposure Limits & Handling
Strict work area ventilation, regular monitoring, and routine staff training form the backbone of occupational safety management. Engineering controls maintain exposure below local OELs, backed by procedural controls during all bagging, drum opening, or reactor charging steps. PPE requirements reflect onsite hazard assessment and current occupational hygiene guidance.
Supply Capacity & Commercial Terms
Production Capacity & Availability
From the perspective of a continuous manufacturer, maleic anhydride supply hinges on the raw material phthalic anhydride or n-butane, and plant reliability. In our experience, catalyst activity, reactor temperature uniformity, and prevention of coking in feedstock vaporization stages determine stable output rates. Maintenance shuts down lines periodically and sometimes spreads batch outputs over multiple tanks, leading to seasonal bottlenecks. During turnaround months or when energy restrictions affect the upstream supply chain, immediate spot capacity drops. Forward booking with established customers and integration of downstream uses, like unsaturated polyester resin plants, improves supply assurance compared to traders who have less visibility into planned production cycles.
Lead Time & Minimum Order Quantity (MOQ)
Lead time reflects batch scheduling, on-site quality review, and loading logistics. Typical lead times for standard grades remain within two to three weeks, provided that current inventory aligns with demand flow. Custom grades or packaging can extend timelines due to line cleaning protocols and off-spec batch quarantine risks. For bulk lots, our MOQ is determined by tank truck or ISO tank volumes, unless drummed variants for export are needed, which follow palletization logic and port regulations.
Packaging Options
Bulk delivery in insulated tank trucks or ISO tanks serves high-volume users with direct melt feed systems. Steel drums, fiber drums, and lined bags support smaller scale or export orders, though drum handling can introduce additional storage challenges in regions with high ambient moisture. Packaging selection depends on purity grade and distance to destination: higher purity or GPC-certified MA requires nitrogen blanketing and tamper-evident closures to prevent hydrolysis and reactivity during transit.
Shipping & Payment Terms
Freight cost structure depends on contract length, volume base, and transport risk. For ocean shipping, insurance, hazardous goods labeling, and paperwork related to Reach or TSCA compliance create further variables. LC at sight or TT advance payment often represent baseline terms for new partnerships; volume off-take and historical performance enable extended payment arrangements.
Pricing Structure & Influencing Factors
Raw Material Cost Composition
Raw material cost comprises the largest proportion of MA factory gate pricing. The n-butane route exposes costs to energy market volatility, refinery turnaround schedules, and regional spot prices for light hydrocarbons. Shifts in the cost of utilities—particularly steam and process air—impact conversion efficiency and byproduct management cost. Catalyst replacement, though not weekly, factors as a consequential semi-fixed cost in process economics.
Fluctuation Causes
Key upstream feedstock shortages, regional plant shutdowns, and unplanned outages result in raw material price swings, with knock-on effects on MA pricing. Changes in regulatory enforcement on VOC emissions and process waste disposal also affect production costs. Strong demand from the unsaturated polyester or plasticizer industries tightens spot availability and raises prices, especially if global olefin or aromatics cycles enter constrained periods. Geopolitical instability near major butane supply hubs can trigger price escalations within days.
Price Difference & Grade Factors
Price differences arise mainly from grade specification, purity profiles, and downstream requirements. High purity or food-additive grades require additional distillation, water content control, and trace contaminant monitoring. Special packaging for high-value applications or certification under GPC, FDA, or REACH frameworks adds compliance costs. Packaging also influences landed cost—bulk shipping lowers unit rates, but repackaging to certified drums for critical applications increases per-unit cost and handling time.
Global Market Analysis & Price Trends
Global Supply & Demand Overview
Globally, capacity growth in Asia—especially China—continues to drive incremental supply, though regional shutdowns for safety or regulatory audits create intermittent gaps. US and EU producers often align output to major resin, lubricant, and food acidulant sectors, with tighter integration into downstream value chains that dampens price volatility. In India and Japan, specialty grade demand sets a price premium, largely due to stricter compliance checks and logistics.
Key Economies Analysis (US/EU/JP/IN/CN)
In the US, demand links primarily to resin and agricultural chemicals. Substantial pipeline access and steady demand secure relatively stable long-term contracts; spot pricing spikes mostly during hurricane season or refinery outages. EU markets show sensitivity to REACH-driven compliance changes and labor constraints. In China, excess capacity sometimes triggers localized overstock discounts, but environmental inspections periodically force rapid supply tightening. Japanese procurement emphasizes quality documentation and batch consistency. India shows robust demand growth from plastics and resins, but faces bottlenecks in domestic production ramp-up and port logistics.
2026 Price Trend Forecast, Data Sources & Methodology
Looking to 2026, slower global economic growth and decarbonization efforts are expected to moderate capacity additions outside of some Asian markets. Energy transition influences input costs, especially for energy-intensive routes. Trade friction or tariff impacts between major producers (particularly US and China) add uncertainty but also prompt some users to lock in multi-year supply deals. Market data from internal production planning, public customs statistics, and third-party monitoring services guides our forward curve expectation: prices show moderate upward pressure, punctuated by short-lived volatility during plant turnaround windows or energy price surges.
Industry News & Regulatory Updates
Recent Market Developments
In the past 12 months, Planed and unplanned plant turnarounds in China and Europe led to supply interruptions. Increased enforcement of local environmental laws forced several older production lines into upgrade or closure. Upstream n-butane cost increases in response to crude volatility tightened margins for several smaller manufacturers, resulting in a broader industry drive toward process modernization and improved utility recovery.
Regulatory Compliance Updates
As a chemical manufacturer, we are observing tighter VOC emissions and stricter waste disposal standards in Asia and Europe. New and revised registration requirements in the EU for classifying and labeling MA-containing mixtures prompt changes in batch recordkeeping and compliance documentation. US regulatory bodies have increased random sampling frequency at ports, with focus on purity, labeling, and packaging for hazardous cargo.
Supplier Response & Mitigation
In production planning, ongoing investment in scrubber and incinerator upgrades responds to emissions tightening. Diversifying raw material sourcing and establishing secondary feedstock contracts buffers against sudden feedstock disruptions or price spikes. Internally, more robust in-process analytics and batch tracking support quick response to any compliance deviations or customer audit requests. Pricing policies now frequently include reviewable escalation clauses to share upstream input costs, while process improvements keep manufactured cost increases within a manageable band.
Application Fields & Grade Selection Guide: Maleic Anhydride (MA)
Application Fields & Grade Matching Guide
Industry Applications
Maleic anhydride serves as a cornerstone intermediate in resin chemistry, polymer manufacturing, coatings, adhesives, agricultural chemicals, and lubricant additive sectors. Each field draws on specific grade properties to optimize chemical reactivity, downstream purification burdens, or regulatory adherence.
- Unsaturated Polyester Resins (UPR): Drives the backbone of both orthophthalic and isophthalic-based polyesters for marine, transport, and construction composites. The resin process tolerates some organic trace impurities, but yellowing and gel time stability push demands for controlled color and minimum organic residue content.
- 1,4-Butanediol (BDO) Synthesis: Used in high-pressure hydrogenation. Feedstock purity impacts catalyst cycle life and fouling; cost tradeoffs are critical at scale. Process designers often define maximum allowable levels for ash and halides.
- Lubricant Additives: Succinic derivatives, especially polyisobutylene succinimides, are produced from maleic anhydride. Trace acid or metallic contaminants can catalyze undesired oligomerization or discoloration. Demand exists for specialty grades with tighter acidity specifications.
- Food & Cosmetic Intermediates: Conversion to fumaric or malic acid follows strict input control. Regulatory frameworks (food additive, pharma, cosmetic) dictate heavy metal, phthalate, and solvent control below region-specific action limits.
- Surface Coatings: Anhydride-modified resins improve crosslinking and weathering. Gel color, water content, and reactivity index influence batch reproducibility for advanced coatings.
Grade-to-Application Mapping
| Application | Common Grade(s) | Key Purity Considerations | Typical Parameters of Interest |
|---|---|---|---|
| Unsaturated Polyester Resins | Industrial, UPR Purity | Color index, organic residue, ash content | Low color (<30 Hazen), minimal ash, liquid & prill forms |
| 1,4-Butanediol Production | High Purity, Hydrogenation Grade | Metal, halide, residual acids | High purity, low catalyst poisons |
| Lubricant Additives | Specialty, Low-Acid | Acid value, metal traces | Ultra-low acid, tight metal limits |
| Food/Cosmetic Intermediates | Refined, Food Grade* | Heavy metals, phthalates | Meets relevant food additive or pharma grade specs |
| Surface Coatings | Industrial, Coatings Purity | Color, hydrolyzable chloride | Low water, clear melt |
*Food/cosmetic applications depend on local laws and certifications, available by request or toll-processing where permitted.
Key Parameters by Application
Industrial production experience shows that the purity, physical form, and impurity profile of maleic anhydride must match the technical demands downstream. Color is vital for appearance-critical uses and batch reproducibility. Water content interferes in organometallic reactions and esterifications. Presence of halides, heavy metals, or organic byproducts may limit use in catalyzed or regulated processes.
Batch variability can arise from feedstock sources or process route drift. Viscosity, melt transition, and flow properties matter for plants using continuous dosing or bulk dissolution into resins. Some users prefer prill form for dust control, others select molten supply chain for reduced dissolution lag.
How to Select the Right Grade
Step 1: Define Application
Establish the end-use environment, chemistry requirements, and whether the maleic anhydride will be further purified or directly reacted. Industrial users often differentiate between bulk resins, fine chemicals, and regulated end-products at the outset.
Step 2: Identify Regulatory Requirements
Check for restrictions or codes imposed by national or customer-specific regulations. Food-grade applications typically require documented control of toxic elements, solvents, and phthalates. Exporters face cross-jurisdiction differences—users should review both local and international standards.
Step 3: Evaluate Purity Needs
Identify which impurities disrupt downstream operations, such as color bodies, acids, or metals. Determine if technical or refined purity grades are compatible with process constraints—or if custom purification is warranted. For catalyst-sensitive processes, explicit upper limits for contaminants usually guide the grade selection, supported by batch certificate review.
Step 4: Consider Volume & Budget
Large-volume resins and BDO plants prioritize supply chain consistency and cost ratios over ultra-purification, provided critical process limits are met. Specialty chemical makers, formulating to pharmaceutical or cosmetic standards, often require negotiated supply with batch documentation and targeted impurity assurance.
Step 5: Request Sample for Validation
Validation trials highlight the fit between supplied grade and end-process. Labs typically test for gel time, color stability, and reactivity in actual use conditions. Pilot and plant managers look for compatibility with existing purification or blending schemes. Reproducibility across multiple sample batches can indicate long-term supply reliability.
Trust & Compliance: Quality Certifications & Procurement Support for Maleic Anhydride (MA)
Quality Compliance & Certifications
Quality Management Certifications
Consistently delivering Maleic Anhydride at a technical and commercial scale requires documented process controls and effective management systems. Production facilities are maintained under recognized quality management programs, where each stage—beginning with the oxidation of butane or benzene through to purification and packaging—operates under validated standard operating procedures. Internal and external audits focus on traceability, batch consistency, change management, and supplier qualification. Certifications, such as ISO 9001, are maintained and applied throughout operations, covering every batch from incoming raw materials to release for shipment.
Product-Specific Certifications
Customers in unsaturated polyester resin, lubricant additives, copolymer resin, or agrochemical intermediates may cite requirements such as REACH registration, food-contact compliance (where applicable), or customer-specific multi-point checks on trace impurities. Product certification is confirmed strictly according to application and region: for example, food- or pharma-grade MA is only made under distinct runs, lines, or plant areas, with segregated raw material tracking and expanded internal release protocols. Regular cross-validation of supplier and end-user requirements forms the baseline for continued supply approval.
Documentation & Reports
Full production documentation routinely accompanies all commercial shipments: certificate of analysis (CoA), certificate of origin, safety data sheets adapted to destination regulations, and compliance statements tied to the supplied product’s actual grade and lot. Batch records contain in-process monitoring results—such as residual maleic acid, phthalic anhydride, or catalyst residue traces—feeding directly into the final CoA. Application-specific use-cases may call for extended impurity profiles or stability assurances based on regulatory, downstream, or export requirements. Change notifications are issued in alignment with critical quality attributes and customer agreements.
Purchase Cooperation Instructions
Stable Production Capacity Supply and Flexible Business Cooperation Plan
Securing MA supply without disruption depends on coordinated raw material contracts, reliable process control, finished product inventory management, and staggered loading schedules. Order forecasting and periodic alignment meetings reduce exposure to upstream volatility. For offtake exceeding plan, manufacturing teams may enact adjustable campaign lengths or switch between primary and backup process routes, based on contract terms and real-time operating data. Block orders or annual procurement plans grant priority scheduling—particularly for critical or regulated applications in resins, additives, or performance chemicals.
Core Production Capacity and Stable Supply Capability
Production planning weighs feedstock availability, process route (butane- or benzene-based), reactor turnaround intervals, and continuous purification capacity. Industrial-grade output is generally prioritized for resin and copolymer demand, while specialty-grade or food-contact grades require dedicated capacity and extra pre-shipment analysis. Customers specifying non-standard impurity limits or extended retest periods must coordinate supply windows and accept added lead time for release. Contingency strategies include parallel inventory locations and load-balancing across multiple production units.
Sample Application Process
Sample requests pass through technical evaluation—confirming grade, downstream use, packaging needs, and special test requirements. Dedicated lab-scale or semi-industrial batches are isolated to avoid cross-contamination. Each sample is accompanied by its batch report, analytical data according to recipient’s requirements, and prompt technical follow-up for early troubleshooting. Feedback cycles improve process adaptation efficiency before full-scale orders are placed, supporting faster downstream evaluation and approvals in resin, polymer, and intermediate synthesis trials.
Detailed Explanation of Flexible Cooperation Mode
Long-term cooperation can involve adjustable purchase volumes, custom logistic routines, shared bufferstocks, and technical support for new formulations or regulatory shifts. Flexibility extends beyond contract clauses: priority dispatch arrangements, returnable packaging, and pre-shipment quality checks can all be negotiated to suit differing storage setups or application timelines. For lower-frequency, project-specific, or trial-based orders, modular production blocks and batch-reserved slots help avoid idle time or overage risk. Technical service teams stay engaged across all cooperation modes to facilitate production changeovers, address specification queries, and optimize performance for evolving customer formulations.
Maleic Anhydride Market Forecast & Technical Support System
Research & Development Trends
Current R&D Hotspots
Recent years have shown research teams focusing on process intensification for both n-butane and benzene oxidation routes. Interest grows in catalyst longevity and selectivity, as catalyst deactivation accounts for a significant share of operating cost and downtime. Multiple labs examine how trace oxygenates, aromatics, or sulfur compounds in feedstocks influence yield and purity. Recovery of heat during gas-phase oxidation remains a target as utilities cost impacts OPEX directly. Downstream, formulators request lower-color, lower-maleic acid grades, prompting both purification process reviews and new approaches for post-reactor separation technology.
Emerging Applications
Polyester resins and BDO remain core demand drivers, but industrial users now investigate routes for biodegradable plastics, water-treatment additives, and agrichemical intermediates. Some manufacturers field requests for higher-purity MA in food-contact or medical-grade polymers, driving reexamination of in-process controls for trace impurities such as phthalates, nitro compounds, or unsaturated aldehydes. Regional downstream sectors in Asia are expanding polyester polyol capacity, which links future MA demand to construction, automotive, and flexible foam production cycles.
Technical Challenges & Breakthroughs
Feedstock cost volatility forces production teams to hedge between n-butane and mixed C4s where available, with process safety and off-gas treatment needing close attention. Fouling and plugging of reactor internals from polymeric byproducts stand out as chronic operational risks, especially in older lines. Ongoing work seeks new catalyst supports with higher mechanical durability and better resistance to coking. Recent pilot plant results show progress in selective condensation, with new scrubber and distillation configurations to decrease recycle streams and improve product color index.
Future Outlook
Market Forecast (3–5 Years)
Based on customer orders and public projects, global demand for MA tracks with growth in unsaturated polyester, modified starch, and tetrahydrofuran value chains. Southeast Asia and India add new downstream units, while US and Middle East plants target cost efficiency by integrating with refinery operations. Policy shifts promoting biodegradable, compostable grades increase requests for food-contact-compliant material, which imposes tighter release criteria for certain specifications. Seasonal and regional utility price swings can influence plant operation rates; in regions with secure feedstock and power supplies, stable production expansion is more feasible.
Technological Evolution
Improved reactor designs using advanced heat transfer surfaces and online process analytics help maintain yield and color under fluctuating load. The switch from air to pure oxygen as an oxidant enhances throughput in some plants but raises fire and explosion risk, requiring revised emergency protocols and operator training. Waste heat recovery and integrated energy management see increased adoption among high-volume producers, with some installations pilot-testing direct steam generation for captive use. As digitalization spreads, predictive maintenance based on process historian data helps reduce unplanned outages tied to fouling or feed variation.
Sustainability & Green Chemistry
Environment officers and production teams collaborate to minimize maleic acid, CO, and formaldehyde emissions. Closed-loop solvent recovery becomes more common, with residue streams routed for on-site incineration or external disposal under certified protocols. Customer interest in bio-based MA has prompted test batches from renewable feedstocks; these remain niche due to cost and scale but guide longer-term R&D priorities. Compliance with REACH, K-REACH, and region-specific toxicological testing shapes both raw material selection and waste management documentation. For large users in water-sensitive regions, zero liquid discharge strategies drive new investments in effluent polishing and recycle.
Technical Support & After-Sales Service
Technical Consultation
Process engineers and formulation specialists routinely consult on grade selection suited to resin, coating, and copolymer manufacturing. Support includes impurity sourcing, reactivity prediction, and pilot plant validation. Troubleshooting covers issues such as batch color drift, off-ratio anhydride-to-acid in hydrolysis, and fouling in storage or transport systems. Recommendations for pre-use storage (minimizing moisture uptake and hydrolysis) draw on observations of regional logistics climates and site hygiene practices.
Application Optimization Support
For downstream conversion, technical staff advise on product handling to avoid agglomeration or hydrolytic degradation under variable ambient conditions. Experience with customer reactors, mixing schemes, and feed protocols supports recommendations tailored to specific resin and copolymerization lines. Industrial users working with recycled PET or bio-based polyols often request guidance on compatibility and reactivity differences against standard grades, particularly where color stability or monomer carryover influences downstream curing or extrusion.
After-Sales Commitment
Batch tracking and recall systems use unique lot traceability linked to internal QC archives. For repeat users, technical specialists offer periodic site visits to review off-spec occurrence, abnormal residue formation, or optimization of process parameters. Complaint response includes comprehensive investigation of transport integrity, container compatibility, and residual moisture or polymerization observed on arrival. Product release criteria follow both internal quality control and final user acceptance protocols, with adjustment windows for region-specific requirements or application-critical grades.
Industrial Commitment to Maleic Anhydride Production
Manufacturing maleic anhydride begins with careful handling of raw materials and technology. Oxidation of n-butane or benzene forms the cornerstone of our process, managed in purpose-built reactors to meet the exacting requirements of modern chemical manufacturing. Every stage, from catalytic oxidation to purification, follows protocols developed by our factory teams and refined through years of process optimization.
Key Applications in Industrial Sectors
Our maleic anhydride integrates into established workflows across unsaturated polyester resin, lubricant additives, agricultural chemicals, and food industry intermediates. In resins, it brings defined reactivity and structural stability, critical for manufacturers of fiberglass-reinforced plastics and automotive parts. The agricultural sector processes MA into succinic acid derivatives, contributing to a reliable supply of specialty chemicals for crop protection and soil conditioning. Additive producers value the anhydride group in formulating lubricants assessed for high-temperature performance. These uses reflect the role MA plays throughout the value chain, from primary synthesis to advanced end-products.
Pursuing Consistency and Quality Assurance
Production control stands at the core of our operations. Every output batch runs through a suite of analytical instruments, including chromatography and spectrometry, to confirm defined purity and low free acid content. Plant personnel monitor oxygen flow rates, catalyst life cycles, and condensation parameters in real time, allowing us to correct process drift before final storage. Records cover every lot from initial charge through to shipment. We design our plant audits and internal laboratory schedules to ensure reproducibility, cutting out the variability that could compromise customer manufacturing runs.
Packaging Expertise and Supply Capability
Our packaging services address bulk and mid-sized requirements. Onsite drum filling, IBC handling, and dedicated tank storage enable us to service polymer plants, blending facilities, and resellers efficiently. Shipments leave under seal, with each container matching our traceability and documentation standards. The logistics team coordinates directly with carriers, adjusting to market cycles and dock requirements. With redundant storage and filling lines, we support consistent delivery even as schedules fluctuate across receiving locations.
Direct Technical Support for Industrial Users
Technical specialists provide input throughout project development, from resin formulation to plant utility integration. Teams collaborate with customer engineers during reformulation, scaling up, and troubleshooting, leveraging first-hand production knowledge to address recurring process questions. Whether customer projects require specific impurity levels, reaction profiles, or blending advice, our plant chemists and applications staff draw on batch histories, side-reaction controls, and additive compatibility studies. Access to our expertise shortens commissioning and reduces trial-and-error for commercial-scale adoption.
Business Value for Manufacturers and Procurement Teams
Consistently supplied maleic anhydride enables production planners to set inventory, downstream blending, and quality schedules with confidence. Buyers gain transparency on batch traceability, cost structure, and delivery dates, reducing surprises in supply and logistics. Industrial customers trust the verified performance and documented control that comes from direct oversight of the production line. Our plant’s capacity investments and process upgrades translate into fewer disruptions, helping procurement groups minimize stockouts and overtime shifts. Process optimization and technical knowledge keep costs controlled across the supply chain, from initial sourcing through end-use conversion.
Industrial FAQ
What are the main industrial applications and chemical properties of Maleic Anhydride (MA)?
What Makes Maleic Anhydride Stand Out in Industrial Use
Maleic anhydride earns its place in modern industry through a combination of reactive chemistry and broad versatility. Our manufacturing team focuses on purity and consistency in every kilogram, knowing that downstream customers expect nothing less – whether formulating resins, additives, or specialty chemicals. MA crystals have a sharp, pungent odor and a high reactivity with water and alcohols, which makes them a valued intermediate for many chemical processes.
Main Industrial Applications
The backbone of most maleic anhydride demand comes from unsaturated polyester resin (UPR) production. This resin class powers applications like fiberglass-reinforced plastics for wind turbine blades, boat hulls, auto parts, and construction panels. Our process tightens control over free acid content and color, addressing direct customer feedback from resin plants to avoid foaming and discoloration during mixing and curing.
Beyond UPRs, maleic anhydride carves out a significant role in lubricant additives. The chemistry behind polyisobutylene succinimide (PIBSA), for example, relies heavily on the anhydride group for an efficient reaction, producing dispersants that keep modern engines running clean. We’ve worked alongside additive formulators, refining particle size parameters and impurity levels, so they can push their detergency packages further with less operational headache.
Another well-established use lies in copolymers for paper sizing. Alkenyl succinic anhydrides (ASAs), formed from the reaction of MA with long-chain hydrocarbons, help papermakers control water absorbency and ink penetration. Producers report that the consistent melting point and controlled residual acidity of our MA batches cut variability during ASA synthesis, improving downstream runnability on fast-moving paper machines.
In agriculture, maleic anhydride serves as a building block in the synthesis of malic acid and succinic acid derivatives, key components in crop protection and plant growth formulations. We maintain established partnerships with downstream processors that manufacture these value-added chemicals, sharing analytical tools that help verify reactivity and batch traceability.
Fumaric and malic acids also trace their commercial routes back to MA. The hydration of maleic anhydride delivers pure maleic acid, which can be isomerized to fumaric acid. Both see frequent use in food acidulant and beverage formulations, where consistent purity and low heavy metal content, hallmarks of our quality assurance, matter to consumer safety standards.
Chemical Properties from a Manufacturer’s View
Maleic anhydride appears as white crystalline flakes or needles, with a melting point near 53°C. It reacts exothermically with water to yield maleic acid, and with alcohols to form half esters. Reactivity toward amines and polyols makes MA a foundation for curing agents, adhesives, and surface modification agents. Its unsaturated double bond allows for copolymerization with vinyl monomers, expanding its use in water treatment, dispersants, and sizing agents.
From a production standpoint, keeping hydrolysis under control during packaging and storage is critical. We deploy moisture barrier liners and sealed drums as standard. Bulk MA shipments run on dedicated railcars or tankers to avoid contamination and maximize shelf-life. Drips or leaks during handling grow costly quickly, given MA’s tendency to solidify on contact with air or moisture; plant operators rely on our technical support for thaw cycles and heating protocols tailored to their equipment.
Meeting Industry Demands
Feedback from industrial users continues to inform our investment in process controls, logistics, and product stewardship. In each application—whether a resin, additive, or agricultural ingredient—the objective stays the same: minimize off-spec batches, meet demanding performance metrics, and keep the end product moving off the line. Our technical team stands ready to address plant challenges, from large batch synthesis to fine-tuned custom applications.
What are the minimum order quantities and available packaging options for Maleic Anhydride (MA)?
Manufacturing Maleic Anhydride at industrial scale takes serious investment in both process management and logistics. Minimum order quantities are set not only to ensure cost-effective production, but also to match the way our material moves through the supply chain. We follow international industry practice by setting our minimum order at one full pallet, which translates to 500 kg or 1,000 kg, depending on the preferred packaging type. This approach keeps logistics efficient and avoids product quality issues that can arise with partial shipments or frequent handling of small lots.
Packaging Options Built for Industry Needs
We pack Maleic Anhydride in solid flake form because that matches the safety profiles most users demand. Our process runs with a closed system, minimizing airborne contamination and controlling moisture uptake. The standard choices are 25 kg polypropylene bags, which come secured on wooden pallets, or 500 kg and 1,000 kg bulk bags (FIBCs). We monitor all packaging for suitability in transportation and storage; anything that could take on moisture or react with the environment earns extra attention from our packing team. Maleic Anhydride is sensitive to moisture, so every bag is lined with high-performance polyethylene to stop clumping and hydrolysis. Each pallet is stretch-wrapped and fitted with visible “Keep Dry” markings to drive home the point that dryness must be maintained throughout transit.
For larger consumers, we also fill tank containers with the molten form. Handling molten Maleic Anhydride is not a casual business. Tanks require heating coils, and every transfer connection passes through a rigorous inspection. This packaging suits customers in resin, additive, and chemical synthesis markets who consume entire container loads rapidly, since molten material doesn’t store well for long periods. We accommodate these specialized needs because that experience flows directly from years of hands-on work with customers operating at full plant scale.
Practical Logistics for Consistent Supply
Palletized bags work best for regional deliveries or warehouse storage. Bulk bags see most use in larger factories where handling equipment is available. We support our partners with the right packaging options so they can run processes without interruptions linked to moisture pickup or material bridging. Questions about shelf life and storage come up often; with factory-fresh supply and tightly managed warehouse rotation, we keep internal stocks moving fast to support customers’ process reliability.
Custom Orders and Technical Support
Some users, especially in the adhesives, polymer, and surfactant sectors, request special packaging or delivery schedules. In these cases, our technical team reviews line capability and packaging supplier availability to ensure the right solution is ready before contract signing. If weight or volume restrictions apply, such as for air or sea freight, we recommend shipment plans based on our history of direct international sales. Our long logistical chain work allows us to adjust for things like specific pallet heights, export-grade pallets, or label requirements. We do not compromise on safety or consistency, as regulatory compliance and material handling safety define our daily routine.
Strong Commitment to Industry Standards
Our manufacturing team prioritizes not just filling orders, but supporting customers through every step—from production through to unloading at the final site. Over the years, feedback from end-users shaped our decisions on what type of packaging meets the most demanding applications. Bulk loading, customized bagging, and different pallet designs result from direct plant experience, not simply catalog offerings. Minimum order quantities reflect both cost control and the best practices for product protection, reducing the chance of contamination or supply-chain interruption.
What are the regulatory compliance requirements and recommended storage conditions for shipping Maleic Anhydride (MA) internationally?
Understanding Compliance Requirements
Shipping Maleic Anhydride across borders means taking regulatory frameworks seriously. Many countries list Maleic Anhydride as a hazardous chemical. We operate under strict observation of the Globally Harmonized System (GHS) and international transport rules including IMDG for sea freight and IATA for air freight. In our shipping documentation, our team assigns the United Nations number (UN 2215) and ensures our Safety Data Sheets (SDS) comply with the most current legal standards. Regulatory documents need to be accurate, readily available, and in the languages required by receiving authorities.
Local rules matter as much as international ones. Some regions enforce additional controls—such as the European Union’s REACH registration or the United States’ TSCA requirements. We maintain registration in relevant chemical inventories and supply pre-shipment samples and paperwork for customs review upon request. Our continuous compliance audits keep our exports in line with current global expectations.
Correct Storage and Shipping Conditions
Our technical department always presses the point: Maleic Anhydride cannot tolerate moisture. Exposure triggers rapid hydrolysis, forming maleic acid and potentially clogging transfer lines, corroding storage equipment, and generating heat. Our product ships in airtight, moisture-proof packaging—typically steel drums or intermediate bulk containers (IBCs) lined with special gaskets. For bulk tank shipments, we use nitrogen-blanketed tanks to eliminate moisture ingress, and all outgoing drums receive high-visibility labeling compliant with hazard communication standards.
Sensitive to temperature swings, Maleic Anhydride remains stable at ambient temperatures. Melting occurs near 52.8°C, so in hotter climates or during summer months, our logistics team uses temperature monitoring and route planning to limit heat exposure during transit. Short-term elevated temperatures pose less risk if containers remain sealed, but prolonged storage above melting point may deform packaging or trigger handling complications. We keep shipment weights balanced and containers secure to avoid leaks or ruptures during handling, and our packaging undergoes regular quality checks as part of our ISO-certified quality management system.
Practical Approaches to Minimizing Transportation Risks
Our operations team works hand-in-hand with global logistics partners to minimize delays at ports and coordinate direct trucking or rail transfers wherever possible. We conduct comprehensive risk assessments for all planned routes. Precaution translates into investment: we maintain emergency response protocols with spill clean-up resources provided for every batch. Alongside our standard transport labels, our containers display detailed emergency procedures.
We document every handoff point from warehouse to container yard. Our process relies on a real-time tracking system that flags irregularities—such as unexpected temperature disruption or prolonged dwell times—prompting immediate intervention. Every MA shipment moves with full traceability from production to delivery. We train drivers and handlers in hazardous goods management, and our team reviews their certification records periodically.
Continual Improvement
We view international shipping as a living process that benefits from review and feedback. Our product stewardship program includes regular scenario drills and in-house audits of labeling, documentation, and container integrity. Regulatory landscapes do not stand still, so we work closely with associations and remain proactive in seeking process improvements. Our customers rely on the integrity of our shipments and our commitment to exceeding not just basic rules, but the evolving expectations of global chemical management.
Technical Support & Inquiry
For product inquiries, sample requests, quotations or after-sales support, please feel free to contact me directly via sales3@liwei-chem.com, +8615365186327 or WhatsApp: +8615365186327